I. Introduction
Surface flashover is of primary concern in high voltage vacuum systems because it often limits the maximum energy deposition into a load. Cathode-initiated surface flashover, the dominant mechanism for most symmetrical anode-cathode-insulator geometries, is relatively well understood. However, an examination of anode-initiated flashover, which is suspected to predominate for geometries where the insulator is oriented at 45° with respect to the anode (positive 45° geometry) due to the enhanced field at the anode triple junction, is less mature. It is noted that this constitutes a very typical geometry for large-scale pulsed power devices, and thus there is interest in gathering experimental evidence for a more complete theoretical basis for anode-initiated flashover. Spectroscopic techniques have previously been used to interrogate cathode-initiated flashovers across planar and cylindrical geometries (0° geometries), leading to the identification of desorbed gasses and cathodoluminescence [1] and quantification of plasma temperatures [2].