Introduction
Light-emitting diodes (LEDs) are expected to become the next generation of solid-state light sources for illumination and communication applications for their numerous advantages, such as eco-friendliness, long life span, high reliability, high efficiency, modulation ability, compact size, short carrier lifetime, low junction capacity, and high endurance of high-frequency injection currents [1]–[3]. Currently, the most widely used approach to generating white LED (WLED) light with high color-rendering index (CRI) is to convert blue LED light into yellow light with yellow-emissive cerium-doped yttrium aluminum garment (Y3Al5O12: Ce3+, YAG) phosphors together with red-emissive phosphors [4], [5] . However, commercial red phosphors suffer from low efficiency in illumination [6] and slow response in communication [7]. To achieve high performance in both illumination and modulation for visible light communication (VLC), quantum dots (QDs) have been proposed to replace red phosphors for their distinguished properties, such as tunable emission wavelength, high quantum efficiency, narrow spectral width at deep-red wavelengths, and short fluorescent lifetime [8], [9]. QDs can compensate for the yellow-dominated spectrum of conventional WLED light to produce a high value of R9 [10]–[12], which is a colorimetric index for the evaluation of saturated red color and is normally used in biomedical and painting identification. By using purely empirical approaches, however, it has been difficult to realize QD-based WLEDs with both high CRI (>90) and R9 (>90) values at given correlated color temperature (CCT) values between 3000 K and 7000 K [1], [9], [13]–[15]. Up to now, no general method is available for generating WLED light with both optimized CRI and R9 values.
In this paper, we describe a general method to simultaneously obtain high CRI and R9 values at a given CCT value for a trichromatic WLED, which consists of three elements: a blue LED, CdSe/ZnS QDs, and YAG phosphors. In comparison with blue QDs [16], a blue LED can provide more stable and controllable output. Alloyed CdSe/ZnS QDs [17] can offer much more stable chemical characteristics than other QDs, such as perovskite QDs [18]. CdSe/ZnS QDs have in fact been adapted and integrated in other optoelectronic devices, such as solar cells [19], electroluminescence-based LEDs [20] , and lasers [21]. YAG phosphors emit a broad spectrum of yellow light and can nicely fill the spectral gap between the blue LED and the CdSe/ZnS QDs. All these elements are commercially available. From the individual emission spectra of these elements and the target white-light spectrum, we are able to determine the right proportions of the QDs and the phosphors for a desired illumination performance. Our preliminary study has confirmed the feasibility of the method [22]. We also investigate the modulation characteristics of the QD-based WLED for VLC applications. By measuring the frequency responses of the three elements, we can synthesize the overall frequency response of the WLED for a given illumination performance. While light sources, such as laser diodes [23], micro LEDs [24], [25], and RGB LEDs [26], [27], have been applied to high-speed VLC, they are expensive and not designed for large-area illumination. A fluorescent WLED source can be a more cost-effective option, which can also offer high color tunability [28], [29]. So far, the studies on fluorescent WLEDs for VLC applications have been focused mainly on their communication performance; there has been no report on optimizing their illumination performance. Our present study provides a general approach of simultaneously optimizing the illumination and communication performances of QD-based fluorescent trichromatic WLEDs.
Optimization of Illumination Performance
We consider a WLED system that consists of a blue LED chip, CdSe/ZnS QDs, and YAG phosphors. Our objective is to determine the proportions of the QDs and the phosphors with an algorithm, so that the WLED light generated have optimized CRI and R9 values for a given CCT value.
2.1 Setup of the WLED
Figure 1(a) shows a lead frame packaged blue LED chip (Hualian Electronics
Co. Ltd) bonded on an aluminum substrate with negative and positive anodes. The dimensions of the chip are
(a) The WLED system used in our study is a blue LED chip covered with CdSe/ZnS QD and YAG phosphor layers. (b) The output light from the WLED system is measured with an integrating sphere connected to a spectral radiation analyzer.
Figures 2(a), (b), and
(c) show the measured absorption and emission spectra, the energy dispersive
X-ray (EDX) analysis, and the X-Ray diffraction (XRD) analysis (Bruker Advance D8 Ew Germany) of the CdSe/ZnS QDs,
respectively. The inset in Fig. 2(a) is a high-resolution transmission
electron microscopy (HRTEM) (FEI Tecnai G2 F30) image of the QDs, which shows that the average diameter of the QDs is
∼7.0 nm. The emission spectrum of the QDs peaks at 625 nm with a narrow full-width-at-half-maximum (FWHM) of 36
nm. Figure 2(b) confirms the chemical components in the CdSe/ZnS QDs and
Fig. 2(c) confirms the purities of CdSe and ZnS in the alloy.
Figures 2(d), (e), and
(f) show the measured absorption and emission spectra, the EDX analysis, and the
XRD analysis of the YAG phosphors, respectively. The inset in Fig. 2(d) is
a scanning electron microscopy (SEM) image of phosphors, which shows that the average diameter of the phosphors is
∼
(a) Absorption and emission spectra, (b) EDX analysis, and (c) XRD analysis of the CdSe/ZnS QDs; (d) absorption and emission spectra, (e) EDX analysis, and (f) XRD analysis of YAG:Ce phosphors. The Insets in (a) and (d) are a HRTEM image of the CdSe/ZnS QDs and an SEM image of the YAG phosphors, respectively.
2.2 Generation of the WLED Spectrum
Figure 3 illustrates the light beams passing through various layers of the
WLED system. The normalized spectrum of the output light from the WLED system
\begin{align}
{I_W}{S_W}(\lambda) &= {I_B}\left[ {{M_B}{S_B}(\lambda) + {M_Q}{S_Q}(\lambda) + {M_P}{S_P}(\lambda)} \right],\tag{1}
\end{align}
\begin{align}
{M_B} &= (1 - {\varepsilon _Q}) - (1 - {\varepsilon _Q}){\varepsilon _P},\tag{2}\\
{M_Q} &= {\varepsilon _Q}{\eta _Q},\tag{3}\\
{M_P} &= (1 - {\varepsilon _Q}){\varepsilon _P}{\eta _p},\tag{4}
\end{align}
\begin{equation}
M = \frac{{{P_e}(\lambda)}}{{{P_a}(\lambda)}} = \frac{{\int_{{380}}^{{780}}{{{P_e}(\lambda)d\lambda
}}}}{{\int_{{380}}^{{780}}{{{P_a}(\lambda)d\lambda }}}},\tag{5}
\end{equation}
Figure 4(a) shows the measured emission spectra of the blue LED, the QDs, and
the phosphors, i.e., \begin{equation}
f = \Delta \times ({a_1}{g_1} + {a_2}{g_2} + {a_3}{g_3}),\tag{6}
\end{equation}
\begin{align}
{g_1} &= 0, {\rm{if}}\,\frac{{|CC{T_{{\rm{est}}}} - CC{T_{tar}}|}}{{CC{T_{tar}}}} < \varepsilon \nonumber\\
{g_1} &= \left(\frac{{|CC{T_{est}} - CC{T_{tar}}|}}{{CC{T_{tar}}}} - \varepsilon \right)/\varepsilon,
{\rm{if}}\,\frac{{|CC{T_{est}} - CC{T_{tar}}|}}{{CC{T_{tar}}}} > \varepsilon\tag{7}
\end{align}
\begin{align}
{g_2} &= 0, {\rm{f}}\,\frac{{|CR{I_{{\rm{est}}}} - CR{I_{tar}}|}}{{CR{I_{tar}}}} < \varepsilon \nonumber\\
{g_2} &= \left(\frac{{|CR{I_{est}} - CR{I_{tar}}|}}{{CR{I_{tar}}}} - \varepsilon \right)/\varepsilon,
{\rm{if}}\,\frac{{|CR{I_{est}} - CR{I_{tar}}|}}{{CR{I_{tar}}}} > \varepsilon \tag{8}
\end{align}
\begin{align}
{g_3} &= 0, {\rm{if}}\,\frac{{|R{9_{{\rm{est}}}} - R{9_{tar}}|}}{{R{9_{tar}}}} < \varepsilon \nonumber\\
{g_3} &= \left(\frac{{|R{9_{est}} - R{9_{tar}}|}}{{R{9_{tar}}}} - \varepsilon \right)/\varepsilon,
{\rm{if}}\,\frac{{|R{9_{est}} - R{9_{tar}}|}}{{R{9_{tar}}}} > \varepsilon \tag{9}
\end{align}
(a) Measured spectra of the blue LED, the QDs, and the phosphors for the WLED. Variations of (b)
According to Eqs. (1)–(
4), the values of
2.3 Numerical Results and Experimental Verification
Figure 5 shows a number of WLED spectra optimized at CCT values ranging from
3000 to 7000 K, which belong to the normal range of white-light CCT values. The CRI and R9 values for each
spectrum are the largest we can achieve at the specified CCT value. As shown in
Fig. 5, the CRI and R9 values increase first and then decrease with an increase in the CCT value with peak
values at CCT = 3530 K. The CRI values in all the generated spectra are larger than 90, which indicates
excellent illumination performance in all these cases. The corresponding values of
Spectral power distribution for CRI optimized WLED with CCT value ranges from 3000 to 7000 K.
We should note that our results are insensitive to the injection current applied to the blue LED. We measured the variation of the emission spectrum of the blue LED with the injection current and found that the peak wavelength of the spectrum shifted by only ∼0.5 nm (from 461.8 to 462.3 nm) with the injection current varying from 20 to 80 mA. The corresponding change in the absorption of the QDs is only ∼0.1%, which can hardly affect the results.
For experimental verification, we consider three WLED spectra with CCT = 3530, 5420, and 6890 K. As shown in
Table 1, the values of
Comparison of calculated and measured spectra of WLEDs with three different target CCT values. (a) 3530 K. (b) 5420 K. (c) 6890 K.
Characterization of Modulation Performance
According to recent surveys, commercial WLED systems can offer bandwidths of approximately 1 MHz [34], [35]. Thanks to the short fluorescence time [36] and the fast response [7] of QDs, QD-based WLEDs should perform better than traditional WLEDs for VLC applications. In this section, we provide an analysis of the frequency response of our WLED. We show explicitly how the frequency responses of the blue LED chip, the QDs, and the phosphors contribute to the frequency response of the WLED. With our analysis, it becomes possible to predict the frequency response of the WLED in optimizing the illumination performance. As such, we can establish a relationship between the illumination performance and the modulation performance of the WLED.
3.1 Calculation of the Frequency Response of the WLED
The frequency response of the WLED, \begin{equation}
R(f) = {M_B}{R_B}(f) + {M_Q}{R_Q}(f) + {M_P}{R_P}(f)\tag{10}
\end{equation}
3.2 Comparison With Measurement Results
Figure 7 shows the experimental setup for the measurement of the frequency
responses of the WLED and its elements. The blue LED was properly biased and driven with a signal generator (RIGOL
DG5072). The output light from the WLED was monitored with a photodetector (THORLABS PDA10A, 150 MHz) and an
oscilloscope (KEYSIGHT, InfiniiVison MSOX6004A). The frequency response of the blue LED alone,
(a) Normalized frequency responses of
Figure 8(c) shows the dependence of the bandwidth of the
illumination-optimized WLED on the CCT value. As shown in Fig. 8(c), the
bandwidths calculated from Eq. (10) (the curve labelled as
“Simulation Result”) are larger than the measured bandwidths (the data points labelled as
“Experimental Result”). The discrepancies can be explained by the wavelength dependence of the
responsivity of the silicon photo-detector [43] used in our experiments. As
shown in the inset of Fig. 8(c), the responsivity decreases with the
wavelength in the visible regime. As a result, the contribution from the blue LED (which has the widest bandwidth) to
the measured frequency response of the WLED is deemphasized, which thus leads to a smaller measured bandwidth. To take
into account the wavelength dependence of the responsivity of the photo-detector in the calculation of the frequency
response of the WLED, we multiply the values 0.16, 0.27, and 0.37 to the three terms in
Eq. (10) that contain
The results shown in Fig. 8 were obtained at an injection current of 50
mA to the blue LED. Although the frequency response of the blue LED is sensitive to the injection current, the
bandwidth of the WLED, which is limited by the phosphors and the QDs, should be relatively insensitive to the
injection current (which is particularly the case at a low CCT where the
Conclusion
We demonstrate a method of optimizing the illumination performance of a tri-chromatic WLED that consists of a blue LED, CdSe/ZnS QDs, and YAG phosphors. This method allows us to easily determine the proper QD and phosphor concentrations for the achievement of optimal illumination performance, i.e., maximum CRI and R9 values, at a specified CCT. In addition, we are able to accurately predict the frequency response of the illumination-optimized WLED from the frequency responses of the blue LED, the QDs, and the phosphors. The calculated frequency response agrees well with the measurement results. As such, we successfully establish a relationship between the illumination performance and the communication performance of the WLED, which can facilitate the implementation of the WLED for both illumination and VLC. While we demonstrate our idea with a specific WLED system, our approach of optimizing the illumination performance together with the process of characterizing the frequency response can be applied to WLEDs based on other light-conversion materials. Without involving massive empirical experimental work, our method, which is based on numerical calculation with preset measurement data, can greatly accelerate the process of finding the desired recipes of WLEDs produced for various illumination and communication applications.
ACKNOWLEDGEMENT
The authors would like to thank H. Yang, W. Zhang, and the Analysis and Testing Center of South University of Science and Technology for their technical assistance.