I. Introduction
Lithiumion battery has attracted much attention because of its high energy density and large charging/discharging current. It is used in a lot of equipment from a small mobile device to a large-scale energy storage system. The dynamic characteristic of the battery heavily depends on its State of Charge (SOC) and current, because the maximum battery current of a large capacity battery is limited by the terminal voltage, which depends on the SOC and the internal impedance of the battery. A numerical simulation plays an important role in the effective usage of the battery and a design of an energy storage system [1]–[8]. An accurate battery model is indispensable to the simulation. The model parameters have a close relation to its life time. A dynamic modeling during its actual operation is important for a development of a self-diagnosis circuit of an energy storage system. An estimation method of a Li-ion battery model, which expresses its transient characteristic, is proposed in this paper. The modeling is carried out using symbolic computation capabilities of Maple ™.