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Enhanced Electromagnetic Interference Shielding Through the Use of Functionalized Carbon-Nanotube-Reactive Polymer Composites | IEEE Journals & Magazine | IEEE Xplore

Enhanced Electromagnetic Interference Shielding Through the Use of Functionalized Carbon-Nanotube-Reactive Polymer Composites


Abstract:

We report on a new principle yielding enhanced electromagnetic shielding, using as an example a composite comprised of carbon nanotubes (CNTs) integrated with a reactive ...Show More

Abstract:

We report on a new principle yielding enhanced electromagnetic shielding, using as an example a composite comprised of carbon nanotubes (CNTs) integrated with a reactive ethylene terpolymer (RET). Such composites were synthesized through the chemical reaction of the functional groups on the CNT with the epoxy linkage of the RET polymer. The main advantages of these composites include good dispersion with low electrical percolation volume fractions (~0.1 volume%), yielding outstanding microwave shielding efficiency for electromagnetic interference applications. The shielding effectiveness was characterized for both single-walled and multiwalled CNT-based composites and was much enhanced in the former. The specific roles of absorption and reflection in determining the total shielding, as a function of the nanotube filling fraction, is also discussed.
Published in: IEEE Transactions on Nanotechnology ( Volume: 9, Issue: 4, July 2010)
Page(s): 464 - 469
Date of Publication: 09 October 2009

ISSN Information:


I. Introduction

The advent of carbon nanotubes (CNTs) and recent studies in polymer–CNT composites [1] has motivated study of their use for electromagnetic interference (EMI) applications as lightweight, high shielding efficiency materials. At the very outset, in EMI shielding, the effects of both reflection and absorption of the incident EM radiation have to be considered [2]. The intensity of the reflected radiation () is related to the difference of the characteristic impedances () of the incident medium (i.e., air of impedance ) and the material () through . The absorption () is quantified through the skin depth (), the extent to which the radiation, of frequency f, penetrates the material through , where is the magnetic permeability and the electrical conductivity. Consequently, while metallic materials (with low and high ) are obviously efficient shielding materials, issues such as cost and bulk preclude their wide-scale application. Such issues have encouraged the use of polymers where the intrinsic poor conductivity could be compensated through the use of filler materials that form a conducting network. (It is to be noted that electrically conducting polymers are currently expensive, difficult to process, and need considerable improvement in their mechanical properties [3].)

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