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Planar, Impedance-Metric NOX Sensor with NiO Sensing Electrode for High Temperature Applications | IEEE Conference Publication | IEEE Xplore

Planar, Impedance-Metric NOX Sensor with NiO Sensing Electrode for High Temperature Applications


Abstract:

In this study, an innovative type of sensor configuration is used which contains an electrolyte constructed of quasi-single crystalline columns, a porous NiO sensing elec...Show More

Abstract:

In this study, an innovative type of sensor configuration is used which contains an electrolyte constructed of quasi-single crystalline columns, a porous NiO sensing electrode (SE) and a conductive Pt reference electrode (RE) deposited on the backside. As electrolyte EB-PVD manufactured discs of FYSZ and PYSZ composition were used. Gas sensing characterization of the sensors was carried with typical flue-gas mixtures in various concentrations. Impedance and potential analysis were done at a frequency range of 100 kHz and 0.005 Hz. Sensors with FYSZ electrolyte could be operated at higher temperatures compared to those with PYSZ electrolytes. The highest achieved sensing temperature in this study was 600degC. NO was successfully detected under the presence of 5%vol. O2 at the maximum operating temperature.
Date of Conference: 10-14 June 2007
Date Added to IEEE Xplore: 24 September 2007
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Conference Location: Lyon, France
References is not available for this document.

1. Introduction

Recently, an urgent need, especially in the automobile industry, for high performance gas sensors has arisen. New exhaust regulations lead to the introduction of high performance catalysts (i.e. SCR or SR-NOX catalysts), which require a precise NOx-monitoring during operation. Furthermore, in other application fields like chemical industry, aeronautics or waste incineration, the use of high temperature NOx-sensors is favoured by new specifications or standards. The requirement for these new generation sensors is to detect total NOx quantitatively at high working temperatures (e.g. 500 to 700°C), without the need for a reference electrode in a different atmosphere [1], , [3]. Therefore the major research goals are the achievement of high temperature, phase-and morphological stability up to 900°C by withholding a high sensitivity towards NOx. Also response time is becoming a more critical design parameter. In this study, we suggest a novel planar NOx-sensor design having an EB-PVD manufactured electrolyte, a RE and a NiO-SE, where both are exposed to the same atmosphere. The application of technical EB-PVD YSZ coatings as electrolyte allows the integration of these sensors into systems (i.e. catalysts) with narrow spacing, allowing placing the sensor at the point of interest. This reduces costs and furthermore decreases the response time of the system.

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References

References is not available for this document.