I. Introduction
Neutralization is a common and important operation in chemical plants, such as biological, wastewater treatment, electrochemistry and precipitation systems. The purpose of neutralization is to adjust the pH value to neutrality for a certain requirement, for example, to minimize the environmental impact in wastewater treatment systems. In the literature, different approaches to control of neutralization processes have been applied, such as modified PI, linear adaptive, model-based, nonlinear adaptive, and predictive adaptive controllers (see [3], [4],. [7] and the references therein). Despite various techniques devoted to improve those classical methods, the performance of neutralization control is not yet adequate due to the inherent nonlinearity of the titration curve and high sensibility to small perturbations near the equivalence Point.