I. Introduction
Electrostatic discharge (ESD) and surface potentials have been and are studied extensively due to the inherent danger to delicate electronic systems. ESD generally starts with charging of a dielectric or other surface commonly through triboelectric charging, whereby two similar or dissimilar materials are rubbed against each other exchanging charges [1]. As an example, removing a dielectric object from foam padding may generate several kilovolts on the surface of the dielectric, which then discharges to nearby conductive objects. While the underlying physics behind the triboelectric effect is not fully understood [2], the relative magnitude of this effect may be characterized in a triboelectric series, which ranks a material’s ability or propensity to exchange and accumulate charges and the relative polarity—i.e., positive/negative—of the charging [3]. Polytetrafluoroethylene (PTFE)—a commonly used material in scientific and chemical processes—is often observed to exhibit a strongly negative charging characteristic; however, other common materials, such as polyamides, polyethylenes, and rubbers, can also be highly charged via tribology. The maximum surface potential, and consequently charge density, is primarily governed by the breakdown strength of the surrounding gas, approximately 30 kV/cm for atmospheric air, which corresponds to a maximum surface charge density of approximately 2–3 nC/cm2. Discharges from these charged surfaces exhibit short rise times with pulsed currents, and as such, it is important to evaluate both the charging and discharge characteristics to determine safe operating conventions and/or storage conditions. Of interest for this study is the case where a dielectric is in a “floating” configuration, whereby no ground exists close enough to influence the electric field between charge and discharge electrodes.