Tuning Epoxy for Medium Frequency Transformer Application: Resin Optimization and Characterization of Nanocomposites at High Temperature

Epoxy resin (EP) insulations are widely considered as potential candidates for various applications. However, it is not suitable for high frequency (HF) and high temperature (HT) applications due to its low thermal conductivity. This research presents the tuning of thermal and electrical properties of EP via resin stoichiometry and incorporation of surface-modified hexagonal boron nitride (h-BN) nanofillers. In this research, the curing agent concentration for pure EP is optimized first based on high thermal stability and sufficiently reliable electrical properties. Second, the optimized pure EP is used as a base material to prepare epoxy/h-BN nanocomposites. Various physicochemical, thermal, and electrical characterizations are performed to analyze the properties of prepared materials. Results show that the higher curing agent concentrations offer a good balance between the thermal and electrical performance of the EP. However, the HF and HT stress exhibits detrimental effects on the breakdown strength and dielectric properties of the materials. Also, the addition of nanofillers further enhances the thermal properties while exhibiting sufficient electrical properties. By the control of resin stoichiometry and nanofiller addition, suitable composites for the HF and HT environment can be realized.