Modeling the Composition of the Pre-Cathode Layer in Dicyanoargentate Buffer Electrolyte without Excess Ligand

Processes of mass-transfer during electro reduction of Ag(I) from electrolytes containing KAg(CN)2 and borate-phosphate-carbonate buffer without an excess of the ligand had been investigated. Concentrations of ions in the volume of electrolyte are calculated, as well as the dependence of pre-cathodic layer composition on the cathodic current density.