Inclusion of Energy Loss in Models of Laser-Irradiated Gold Films via Classical Molecular Dynamics

The structural evolution of laser-excited systems of gold has previously been measured through ultrafast MeV electron diffraction. 1 - 3 However, there has been a long-standing inability of atomistic simulations to provide a consistent picture of the melt process, concluding in large discrepancies between the predicted threshold energy density for complete melt, as well as the transition between heterogeneous and homogeneous melting. 1 We make use of two-temperature classical molecular dynamics simulations utilizing two highly successful interatomic potentials and reproduce electron diffraction data presented by Mo et al.. We recreate the experimental electron diffraction data employing both a constant and temperature-dependent electron-ion equilibration rate. In all cases we are able to match time-resolved electron diffraction data, and find consistency between atomistic simulations and experiments, only by allowing laser energy to be transported away from the interaction region for the duration of the melt process. This additional energy-loss pathway, which scales strongly with laser fluence, we attribute to hot electrons leaving the target during melt before refluxing.