Effect of alumina tri-hydrate surface modification on liquid permeation and electrical performance of silicone rubber

This paper investigates the liquid permeation performance of silicone rubber containing alumina tri-hydrate (ATH) that has been modified with N-[3-(trimethoxysilyl) propyl] aniline (Y-9669). From the change in weight during immersion in water, saline solution or nitric acid, and during subsequent drying in air as well as a second immersion test, it is revealed that the majority of the absorbed liquid exists in filler and interface for silicone rubber with original ATH. Surface modification of ATH filler can protect silicone rubber from liquid permeation. It is easier for liquid to permeate into silicone rubber than to escape from it due to the hydrophobicity of the silicone rubber matrix. A cycle of immersion and drying is found to have little impact on subsequent immersion in the case of water and saline solutions; however, damage inflicted on the matrix and filler by nitric acid means that the rate of permeation increases during subsequent immersion. The volume resistivity and surface resistivity of samples with unmodified ATH also decrease more appreciably than those with modified ATH after a cycle of immersion and air drying due to the amount of the residual absorbed liquid.