Magnetocaloric Effect of Amorphous Gd65Fe10Co10Al10X5 (X = Al, Si, B) Alloys

Gd-based amorphous alloys with addition of metals and metalloids are interesting materials from the point of view of magnetic and magnetocaloric properties. Moreover, they usually possess high corrosion resistance and good mechanical properties. A series of Gd
₆₅
Fe
₁₀
Co
₁₀
Al
₁₀
X
₅
(X = Al, Si, B) alloys was synthesized by melt-spinning. The amorphous structure of ribbons was confirmed by X-ray diffraction. Calorimetric curves allowed to determine crystallization temperatures, which are in the range of 260°C–303°C. The temperature dependences of the magnetic entropy changes were calculated from series of isothermal magnetization curves using Maxwell relation. Maximum value of the magnetic entropy change for the magnetic field change from 0 to 5 T is 7.1 J kg
\(^{\mathrm {-1}}\)
K
\(^{\mathrm {-1}}\)
for X = B, whereas the related refrigerant capacity (RC) is 748 J kg
\(^{\mathrm {-1}}\)
. For Gd
₆₅
Fe
₁₀
Co
₁₀
Al
₁₅
and Gd
₆₅
Fe
₁₀
Co
₁₀
Al
₁₀
Si
₅
alloys, the maximum values of magnetic entropy change reached 6.0 and 5.9 J kg
\(^{\mathrm {\mathbf {-1}}}\)
K
\(^{\mathrm {\mathbf {-1}}^{\vphantom {)}}}\)
, while the obtained values for
RC
parameter were 700 and 698 J kg
\(^{\mathrm {\mathbf {-1}}}\)
, respectively.