I. Introduction
Phase-change random access memory (PCRAM) devices, associated with its companions such as resistive RAM (ReRAM), ferroelectric RAM (FeRAM), and magnetic RAM (MRAM), have recently been regarded as the most promising substitutions for conventional dynamic RAM (DRAM) and static RAM (SRAM). Previously successful application of phase-change materials (PCMs) on rewritable optical disks [1] has accumulated a wealth of knowledge regarding the optical-thermo properties of PCMs and corresponding fabrication techniques [2], [3]. Subsequent research on PCRAM devices has naturally inherited such heritage and, therefore, accelerated the commercialization of PCRAM prior to other nonvolatile RAMs [4]. The total number of phase-change memory-related research papers and technical patents published within the year 2021 already exceeded 1200 and 900, respectively, implying the bright future of PCRAMs.