Neutron diffraction studies of rare earth transition metal nitrides

Novel high-performance permanent magnets have been found as the result of nitrogenation of rare-earth (RE)-iron-based phases, including RE/sub 2/Fe/sub 17/ and REFe/sub 12-x/TM/sub x/. Neutron diffraction has been used to study the changes in structure which accompany the nitrogenation. While some of these, like the change in lattice constants and cell volume can also be determined by X-ray diffraction, the other changes, including nitrogen location and occupation, and interatomic bond lengths, can only be determined by Rietveld analysis of neutron data. These investigations and a comparison of these phases with the parent phases and with Nd/sub 2/Fe/sub 14/B reveal interesting trends, and may provide significant insight into the physics of these materials.<
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